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Adsorption of N,N-dimethylamine from aqueous solutions by a metal organic framework, MOF – 235

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Authors
Beltrán-Suito, Rodrigo
Pinedo-Flores, Angela
Bravo-Hualpa, Fabiola
Ramos-Muñoz, Jorge
Sun-Kou, María del Rosario
Issue Date
2018
Keywords
Dimethylamine
Water treatment
MOF-235
Adsorption
xmlui.metadata.dc.contributor.email
msun@pucp.edu.pe

Metadata
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Publisher
Taylor and Francis Inc.
Journal
Journal of Dispersion Science and Technology
URI
http://hdl.handle.net/10757/624712
DOI
10.1080/01932691.2018.1489275
Additional Links
https://www.tandfonline.com/doi/full/10.1080/01932691.2018.1489275
Abstract
Water-resistant MOF-235 was used to adsorb N,N-dimethylamine (DMA) from aqueous solutions. It was synthesized from terephthalic acid and FeCl3.6H2O under air-free conditions and characterized by its crystalline structure, functional groups and temperature resistance. The kinetic data results were best adjusted to the pseudo-second order model (R2>0.963). The best-fit isotherm, Langmuir model, suggested the adsorption of DMA is localized on homogenously distributed active sites on the surface. This fit was confirmed by the value of β = 1 on the Redlich-Peterson model. Our study suggests that the manipulation of novel materials such as MOF-235 promises new avenues for water treatment solutions. Schematic structure of MOF-235 and its application as adsorbent.
Type
info:eu-repo/semantics/article
Rights
info:eu-repo/semantics/restrictedAccess
Language
eng
Description
El texto completo de este trabajo no está disponible en el Repositorio Académico UPC por restricciones de la casa editorial donde ha sido publicado.
ISSN
0193-2691
1532-2351
ae974a485f413a2113503eed53cd6c53
10.1080/01932691.2018.1489275
Scopus Count
Collections
Ingeniería Industrial

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